Fabrication and characterization of hybrid thermoelectric materials based on aligned nanowires

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초록

This study introduces the synthesis of a hybrid thermoelectric material with enhanced conductivity and a high Seebeck coefficient, leveraging the properties of Te nanowires (NWs) and the conductive polymer PEDOT:PSS. Te NWs were synthesized using the galvanic displacement reaction. To further enhance conductivity, Ag-Te NWs were synthesized under optimized conditions via the Ag topotactic reaction, achieving desired results within 7 min using ethylene glycol and AgNO3. This hybrid material exhibited an electrical conductivity of 463 S/cm, a Seebeck coefficient of 69.5 mu V/K at 300 K, and a power factor of 260 mu W/mK2. These metrics surpassed those of conventional Te/PEDOT:PSS hybrids by a factor of 3.6, highlighting the superior performance of our approach. This study represents a significant advancement in thermoelectric materials, improving both conductivity and efficiency.

키워드

thermoelectrics; hybrid thermoelectrics; te nanowire; galvanic displacement reaction; topotactic reaction; POWER; TEMPERATURE
제목
Fabrication and characterization of hybrid thermoelectric materials based on aligned nanowires
저자
Lee, Min-Jeong; Kim, Chae Yoon; Lim, Jae-Hong
DOI
10.3389/fchem.2024.1407129
발행일
2024-09
유형
Article
저널명
Frontiers in Chemistry
권
12