The mechanisms and topologies of Ru-based water oxidation catalysts: A comprehensive review

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초록

A water-splitting device is based on the activity of water oxidation catalysts. Water oxidation catalysts have been designed using different strategies to form multiple topologies. The catalysts vary in their function depending on their coordination flexibility, steric hindrance, and carboxylate ligands. The onset potential of the water -oxidation catalysts can be lowered by the addition of functional groups with negative charges. The normal configuration of the transition metal complex should be distorted to form an open site that can conveniently bind to the substrates. In this review, we have discussed the mechanism of Ru-based water oxidation catalysts with different topologies beneficial for the conversion of the substrate.

키워드

Water oxidation catalystRu-based catalystTopologyLigandsReaction mechanismMOLECULAR RUTHENIUM CATALYSTSPOLYPYRIDINE COMPLEXESHIGHLY EFFICIENTREDOX PROPERTIESANIONIC LIGANDSPHOTOISOMERIZATIONINTERMEDIATEASSEMBLIESSILATRANEPATHWAY
제목
The mechanisms and topologies of Ru-based water oxidation catalysts: A comprehensive review
저자
Nguyen, Quoc HaiTa, Qui Thanh HoaiTran, Ngo
DOI
10.1016/j.ceramint.2022.11.228
발행일
2023-02
유형
Review
저널명
Ceramics International
49
3
페이지
4030 ~ 4045