Facile Preparation of A-D-A Type Through-Space Charge Transfer Molecules Utilizing Indoloindoles

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초록

This study presents a straightforward synthetic pathway for the preparation of through‐space charge transfer (TSCT) molecules, utilizing an IDID core as the donor, connected to double bridges. The IDID core, known for its enhanced donor properties, incorporates two sites that facilitate a concise synthetic approach for the introduction of bridges in the acceptor‐donor‐acceptor design. Computational studies played a pivotal role in guiding our design, predicting favorable energy levels and TSCT characteristics. Experimental validation of TSCT characteristics was achieved through measurements of photophysical properties.

키워드

IndoloindoleThermally activated delayed fluorescenceThrough-space charge-transferACTIVATED DELAYED FLUORESCENCELIGHT-EMITTING-DIODESAGGREGATION-INDUCED EMISSIONSTRATEGYSTATEDONOR
제목
Facile Preparation of A-D-A Type Through-Space Charge Transfer Molecules Utilizing Indoloindoles
저자
Kim, EunjungHan, HyewonHong, Wan PyoLee, Chung Whan
DOI
10.1002/ajoc.202400284
발행일
2024-09
유형
Article
저널명
Asian Journal of Organic Chemistry
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