Top-seeded solid-state single crystal growth of 0.75(Na<sub>0.5</sub>Bi<sub>0.5</sub>)TiO<sub>3</sub>-0.25SrTiO<sub>3</s ub> single crystals in oxygen and their characterization

  • Le, Phan Gia
  • Lee, Jong-Sook
  • Kim, Hwang-Pill
  • Jo, Wook
  • Xie, Hang
  • 외 3명
Citations

WEB OF SCIENCE

4
Citations

SCOPUS

4

초록

In this present work, 0.75(Na0.5Bi0.5)TiO3-0.25SrTiO(3) single crystals were grown by top-seeded solid-state crystal growth under an oxygen atmosphere. Growth in oxygen resulted in improved single-crystal growth and density compared to single crystals previously grown in air. X-ray diffraction revealed the simultaneous presence of tetragonal and cubic phases in the crystal while Raman scattering suggested the presence of rhombohedral and tetragonal phases. Piezoresponse force microscopy and electrostatic force microscopy show that the single crystal is in an ergodic relaxor state and electrostatic force microscopy shows that ferroelectric domains can be induced by an electric field. Dielectric property measurements show behaviour typical of an (Na0.5Bi0.5)TiO3-type relaxor material. Polarization and strain vs. electric field hysteresis measurements show that the single crystal is an incipient ferroelectric. A maximum strain of 0.48% was obtained at an electric field of 3.5 kV/mm, giving S-max/E-max = 1365 pm/V, which is an enhancement of 32% compared to 0.75(Na0.5Bi0.5)TiO3-0.25SrTiO(3) single crystals grown in air.

키워드

(Na0.5Bi0.5)TiO3Single crystalPiezoelectric propertiesFerroelectric propertiesActuatorsMORPHOTROPIC PHASE-BOUNDARYX-RAY-DIFFRACTIONELECTRICAL-PROPERTIESPARAELECTRIC PHASEDOMAIN-STRUCTURESRELAXOR BEHAVIORPLZT CERAMICSTEMPERATURETRANSITIONSPEROVSKITE
제목
Top-seeded solid-state single crystal growth of 0.75(Na<sub>0.5</sub>Bi<sub>0.5</sub>)TiO<sub>3</sub>-0.25SrTiO<sub>3</s ub> single crystals in oxygen and their characterization
저자
Le, Phan GiaLee, Jong-SookKim, Hwang-PillJo, WookXie, HangChang, YunfeiGe, WenweiFisher, John G.
DOI
10.1007/s43207-024-00418-5
발행일
2024-06
유형
Article; Early Access
저널명
한국세라믹학회지
61
6
페이지
1036 ~ 1049