Improved carrier transport properties by I-doping in n-type Cu0.008Bi2Te2.7Se0.3 thermoelectric alloys

  • Lee K.H.
  • Kim H.-S.
  • Choo S.-S.
  • Shin W.H.
  • Lim J.-H.
  • 외 2명
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초록

The addition of Cu becomes essential in polycrystalline n-type Bi2(Te,Se)3-based alloys since it is known to enhance stability of carrier transport properties as well as thermoelectric performance. However, a way to further optimize is necessary owing to the limited controllability of transport parameters by Cu addition. Herein, we present improved carrier transport properties via I-doping in Cu0.008Bi2Te2.7Se0.3. Weighted mobility and effective mass are increased simultaneously by small amount doping of I at Te/Se-site. As a result, ~15% increased power factor and high average thermoelectric figure of merit (zT) of 0.79 were obtained in a wide temperature range. © 2020

키워드

Bi2(Te,Se)3Effective massIodineThermoelectricWeighted mobilityCarrier transportThermoelectricityEffective massPolycrystallinePower factorsThermoelectric alloysThermoelectric figure of meritThermoelectric performanceTransport parametersWide temperature rangesTransport properties
제목
Improved carrier transport properties by I-doping in n-type Cu0.008Bi2Te2.7Se0.3 thermoelectric alloys
저자
Lee K.H.Kim H.-S.Choo S.-S.Shin W.H.Lim J.-H.Kim S.W.Kim S.-I.
DOI
10.1016/j.scriptamat.2020.04.030
발행일
2020-09
유형
Article
저널명
Scripta Materialia
186
페이지
357 ~ 361